The most common deviation from structured programming is early exit from a function or loop. At the level of functions, this is a return statement. At the level of loops, this is a break statement (terminate the loop) or continue statement (terminate the current iteration, proceed with next iteration). In structured programming, these can be replicated by adding additional branches or tests, but for returns from nested code this can add significant complexity. C is an early and prominent example of these constructs. Some newer languages also have "labeled breaks", which allow breaking out of more than just the innermost loop. Exceptions also allow early exit, but have further consequences, and thus are treated below.
