Alexandropoulou began her involvement in film industry as a director's personal assistant for Bellocchio and Paolo Virzi. In 1993 she worked on Marco Bellocchio's film Il sogno della farfalla while the following year she worked on the production of the Italian drama film With Closed Eyes (written and directed by Francesca Archibugi). In 2000 she wrote and directed the short film I fantastici Boors which was distinguished in Trani and Capalbio Film Festival.
