In his position as archdeacon, Scott was a member of the Legislative Council (ranking next behind the Lieutenant Governor) and had almost complete control of all church matters. The Colonial Office appointed him King's Visitor to schools and so he became responsible for public education throughout the colony. His educational policy was guided by the principle that the church and education were inseparably connected and the funds to sustain them were administered by the same trustees. Since this view was shared by the Colonial Office, the Governor Bathurst, in March 1826, created the Corporation of the Trustees of Church and School Lands, granting one-seventh of the lands of New South Wales to the corporation for the purposes of the Church of England and education in the colony. Scott became the ex officio Vice-President (the President being the Governor.)
