An ideal surface is flat, rigid, perfectly smooth, chemically homogeneous, and has zero contact angle hysteresis. Zero hysteresis implies the advancing and receding contact angles are equal. In other words, only one thermodynamically stable contact angle exists. When a drop of liquid is placed on such a surface, the characteristic contact angle is formed as depicted in Figure 1. Furthermore, on an ideal surface, the drop will return to its original shape if it is disturbed.Johnson, Rulon E. (1993) in Wettability Ed. Berg, John. C. New York, NY: Marcel Dekker, Inc. The following derivations apply only to ideal solid surfaces; they are only valid for the state in which the interfaces are not moving and the phase boundary line exists in equilibrium.
