She was born Albine Hélène de Vassal in Paris. Her cousin was Régis de Cambacérès. On 19 February 1797, at age 17, she married Jean-Pierre Bignon; they divorced in 1799. On 18 August 1800, at age 20, she married Daniel Roger. In December 1809, she gave birth to a son, Tristan Charles François Napoléon de Montholon-Sémonville. A second son, Napoléon Charles Tristan de Montholon-Sémonville, was born on 3 October 1810. Both sons being named "Charles", "Tristan", and "de Montholon-Sémonville" suggests they were fathered by Montholon before Albine married him on 2 July 1812, two months after divorcing Roger. She gave birth to her third son, Charles-François-Frédéric, in 1814.
