On 10 April 2019, de Pena signed for Ukrainian Premier League vice champions Dynamo Kyiv as a free agent. With the club he won the 2019–20 Ukrainian Cup and the 2019 and 2020 Ukrainian Super Cups. On 17 April 2021, he scored the winning goal by penalty during the derby against Shakhtar Donetsk in the 2020–21 season at the NSC Olimpiyskiy. On 25 April 2021, he won the league with Dynamo Kyiv.
