In 2016, Ana Luiza started her season competing at the 2016 Gracia Cup in Budapest and finished 2nd in the all-around, she qualified to 4 event finals and finished 2nd in hoop, 4th in ball and 3rd in clubs, ribbon. On February 17–22, she competed at the 2016 Grand Prix Moscow finishing 19th in the all-around with a total of 66.916 points.. On March 17–20, Ana Luiza then competed at the 2016 Lisboa World Cup where she finished 15th in the all-around. On April 1–3, Ana Luiza competed at the 2016 Pesaro World Cup where she finished 20th in the all-around with a total of 69.050 points. On April 21–22, Ana Luiza won an Olympics license by finishing sixth amongst a top 8 selection of highest score for non qualified gymnasts at the 2016 Gymnastics Olympic Test Event held in Rio de Janeiro. On May 13–15, Ana Luiza then finished 7th in the all-around at the 2016 Grand Prix Bucharest (a new PB: 70.750) behind Israel's Victoria Veinberg Filanovsky. On May 27–29, Ana Luiza finished 10th in the all-around at the 2016 Sofia World Cup with a total of 69.250 points. On July 8–10, Ana Luiza then finished 22nd in the all-around at the 2016 Kazan World Cup. On September 23–24, Ana Luiza culminated her season with her competition at the 2016 Grand Prix Final in Eilat, where she finished 8th in the all-around with a total of 67.683 points. On August 19–20, Ana Luiza competed at the 2016 Summer Olympics held in Rio de Janeiro, Brazil. She finished 22nd in the rhythmic gymnastics individual all-around qualifications and did not advance into the top 10 finals.
