Giorio was born and grew up in Vicenza (Italy). She attended the “Liceo Scientifico G.B. Quadri” where she became interested in Chemistry. She then studied at the University of Padova where she received her Bachelors degree in 2006 and Masters degree in 2008 in chemistry. Giorio attained a PhD in Molecular Sciences from the University of Padova on 28 February 2012.