Gallium
Physical properties

Elemental gallium is not found in nature, but it is easily obtained by smelting. Very pure gallium is a silvery blue metal that fractures conchoidally like glass. Gallium's volume expands by 3.10% when it changes from a liquid to a solid so care must be taken when storing it in containers that may rupture when it changes state. Gallium shares the higher-density liquid state with a short list of other materials that includes water, silicon, germanium, bismuth, and plutonium.

Gallium forms alloys with most metals. It readily diffuses into cracks or grain boundaries of some metals such as aluminium, aluminium – zinc alloys and steel, causing extreme loss of strength and ductility called liquid metal embrittlement.

The melting point of gallium, at 302.9146 K (29.7646 °C, 85.5763 °F), is just above room temperature, and is approximately the same as the average summer daytime temperatures in Earth's mid-latitudes. This melting point (mp) is one of the formal temperature reference points in the International Temperature Scale of 1990 (ITS-90) established by the International Bureau of Weights and Measures (BIPM). The triple point of gallium, 302.9166 K (29.7666 °C, 85.5799 °F), is used by the US National Institute of Standards and Technology (NIST) in preference to the melting point.

The melting point of gallium allows it to melt in the human hand, and then solidify if removed. The liquid metal has a strong tendency to supercool below its melting point / freezing point: Ga nanoparticles can be kept in the liquid state below 90 K. Seeding with a crystal helps to initiate freezing. Gallium is one of the four non-radioactive metals (with caesium, rubidium, and mercury) that are known to be liquid at, or near, normal room temperature. Of the four, gallium is the only one that is neither highly reactive (as are rubidium and caesium) nor highly toxic (as is mercury) and can, therefore, be used in metal-in-glass high-temperature thermometers. It is also notable for having one of the largest liquid ranges for a metal, and for having (unlike mercury) a low vapor pressure at high temperatures. Gallium's boiling point, 2676 K, is nearly nine times higher than its melting point on the absolute scale, the greatest ratio between melting point and boiling point of any element. Unlike mercury, liquid gallium metal wets glass and skin, along with most other materials (with the exceptions of quartz, graphite, gallium(III) oxide and PTFE), making it mechanically more difficult to handle even though it is substantially less toxic and requires far fewer precautions than mercury. Gallium painted onto glass is a brilliant mirror. For this reason as well as the metal contamination and freezing-expansion problems, samples of gallium metal are usually supplied in polyethylene packets within other containers.

Gallium does not crystallize in any of the simple crystal structures. The stable phase under normal conditions is orthorhombic with 8 atoms in the conventional unit cell. Within a unit cell, each atom has only one nearest neighbor (at a distance of 244 pm). The remaining six unit cell neighbors are spaced 27, 30 and 39 pm farther away, and they are grouped in pairs with the same distance. Many stable and metastable phases are found as function of temperature and pressure.

The bonding between the two nearest neighbors is covalent; hence Ga dimers are seen as the fundamental building blocks of the crystal. This explains the low melting point relative to the neighbor elements, aluminium and indium. This structure is strikingly similar to that of iodine and may form because of interactions between the single 4p electrons of gallium atoms, further away from the nucleus than the 4s electrons and the 3d core. This phenomenon recurs with mercury with its "pseudo-noble-gas" 4f 5d 6s electron configuration, which is liquid at room temperature. The 3d electrons do not shield the outer electrons very well from the nucleus and hence the first ionisation energy of gallium is greater than that of aluminium. Ga dimers do not persist in the liquid state and liquid gallium exhibits a complex low-coordinated structure in which each gallium atom is surrounded by 10 others, rather than 11–12 neighbors typical of most liquid metals.

The physical properties of gallium are highly anisotropic, i.e. have different values along the three major crystallographic axes a, b, and c (see table), producing a significant difference between the linear (α) and volume thermal expansion coefficients. The properties of gallium are strongly temperature-dependent, particularly near the melting point. For example, the coefficient of thermal expansion increases by several hundred percent upon melting.
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