Primary color
Psychological primaries

The opponent process was proposed by Ewald Hering in which he described the four unique hues (later called psychological primaries in some contexts): red, green, yellow and blue. To Hering, the unique hues appeared as pure colors, while all others were "psychological mixes" of two of them. Furthermore, these colors were organized in "opponent" pairs, red vs. green and yellow vs. blue so that mixing could occur across pairs (e.g., a yellowish green or a yellowish red) but not within a pair (i.e., reddish green cannot be imagined). An achromatic opponent process along black and white is also part of Hering's explanation of color perception. Hering asserted that we did not know why these color relationships were true but knew that they were. Although there is a great deal of evidence for the opponent process in the form of neural mechanisms, there is currently no clear mapping of the psychological primaries to neural correlates.

The psychological primaries were applied by Richard S. Hunter as the primaries for Hunter L,a,b colorspace that led to the creation of CIELAB. The Natural Color System is also directly inspired by the psychological primaries.
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