Solid
Ceramics

Ceramic solids are composed of inorganic compounds, usually oxides of chemical elements. They are chemically inert, and often are capable of withstanding chemical erosion that occurs in an acidic or caustic environment. Ceramics generally can withstand high temperatures ranging from 1,000 to 1,600 °C (1,830 to 2,910 °F). Exceptions include non-oxide inorganic materials, such as nitrides, borides and carbides.

Traditional ceramic raw materials include clay minerals such as kaolinite, more recent materials include aluminium oxide (alumina). The modern ceramic materials, which are classified as advanced ceramics, include silicon carbide and tungsten carbide. Both are valued for their abrasion resistance, and hence find use in such applications as the wear plates of crushing equipment in mining operations.

Most ceramic materials, such as alumina and its compounds, are formed from fine powders, yielding a fine grained polycrystalline microstructure that is filled with light-scattering centers comparable to the wavelength of visible light. Thus, they are generally opaque materials, as opposed to transparent materials. Recent nanoscale (e.g. sol-gel) technology has, however, made possible the production of polycrystalline transparent ceramics such as transparent alumina and alumina compounds for such applications as high-power lasers. Advanced ceramics are also used in the medicine, electrical and electronics industries.

Ceramic engineering is the science and technology of creating solid-state ceramic materials, parts and devices. This is done either by the action of heat, or, at lower temperatures, using precipitation reactions from chemical solutions. The term includes the purification of raw materials, the study and production of the chemical compounds concerned, their formation into components, and the study of their structure, composition and properties.

Mechanically speaking, ceramic materials are brittle, hard, strong in compression and weak in shearing and tension. Brittle materials may exhibit significant tensile strength by supporting a static load. Toughness indicates how much energy a material can absorb before mechanical failure, while fracture toughness (denoted K) describes the ability of a material with inherent microstructural flaws to resist fracture via crack growth and propagation. If a material has a large value of fracture toughness, the basic principles of fracture mechanics suggest that it will most likely undergo ductile fracture. Brittle fracture is very characteristic of most ceramic and glass-ceramic materials that typically exhibit low (and inconsistent) values of K.

For an example of applications of ceramics, the extreme hardness of zirconia is utilized in the manufacture of knife blades, as well as other industrial cutting tools. Ceramics such as alumina, boron carbide and silicon carbide have been used in bulletproof vests to repel large-caliber rifle fire. Silicon nitride parts are used in ceramic ball bearings, where their high hardness makes them wear resistant. In general, ceramics are also chemically resistant and can be used in wet environments where steel bearings would be susceptible to oxidation (or rust).

As another example of ceramic applications, in the early 1980s, Toyota researched production of an adiabatic ceramic engine with an operating temperature of over 6,000 °F (3,320 °C). Ceramic engines do not require a cooling system and hence allow a major weight reduction and therefore greater fuel efficiency. In a conventional metallic engine, much of the energy released from the fuel must be dissipated as waste heat in order to prevent a meltdown of the metallic parts. Work is also being done in developing ceramic parts for gas turbine engines. Turbine engines made with ceramics could operate more efficiently, giving aircraft greater range and payload for a set amount of fuel. Such engines are not in production, however, because the manufacturing of ceramic parts in the sufficient precision and durability is difficult and costly. Processing methods often result in a wide distribution of microscopic flaws that frequently play a detrimental role in the sintering process, resulting in the proliferation of cracks, and ultimate mechanical failure.
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