Bronze
History

The discovery of bronze enabled people to create metal objects that were harder and more durable than previously possible. Bronze tools, weapons, armor, and building materials such as decorative tiles were harder and more durable than their stone and copper (" Chalcolithic ") predecessors. Initially, bronze was made out of copper and arsenic or from naturally or artificially mixed ores of those metals, forming arsenic bronze.

The earliest known arsenic-copper-alloy artifacts come from a Yahya Culture (Period V 3800-3400 BCE) site, at Tal-i-Iblis on the Iranian plateau, and were smelted from native arsenical copper and copper-arsenides, such as algodonite and domeykite.

The earliest tin-copper-alloy artifact has been dated to c. 4650 BC, in a Vinča culture site in Pločnik (Serbia), and believed to have been smelted from a natural tin-copper ore, stannite.

Other early examples date to the late 4th millennium BC in Egypt, Susa (Iran) and some ancient sites in China, Luristan (Iran), Tepe Sialk (Iran), Mundigak (Afghanistan), and Mesopotamia (Iraq).

Tin bronze was superior to arsenic bronze in that the alloying process could be more easily controlled, and the resulting alloy was stronger and easier to cast. Also, unlike those of arsenic, metallic tin and the fumes from tin refining are not toxic.

Tin became the major non-copper ingredient of bronze in the late 3rd millennium BC. Ores of copper and the far rarer tin are not often found together (exceptions include Cornwall in the United Kingdom, one ancient site in Thailand and one in Iran), so serious bronze work has always involved trade with other regions. Tin sources and trade in ancient times had a major influence on the development of cultures. In Europe, a major source of tin was the British deposits of ore in Cornwall, which were traded as far as Phoenicia in the eastern Mediterranean. In many parts of the world, large hoards of bronze artifacts are found, suggesting that bronze also represented a store of value and an indicator of social status. In Europe, large hoards of bronze tools, typically socketed axes (illustrated above), are found, which mostly show no signs of wear. With Chinese ritual bronzes, which are documented in the inscriptions they carry and from other sources, the case is clear. These were made in enormous quantities for elite burials, and also used by the living for ritual offerings.
startend:quotation