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Gunpowder

In Song China (960–1279), weapons known as ' thunder crash bombs ' (震天雷) were created when soldiers packed gunpowder into ceramic or metal containers fitted with fuses. A 1044 military book, Wujing Zongyao (Compilation of Military Classics), described various gunpowder recipes in which one can find, according to Joseph Needham, the prototype of the modern hand grenade.

The shells (pào) are made of cast iron, as large as a bowl and shaped like a ball. Inside they contain half a pound of 'divine fire' (shén huǒ, gunpowder). They are sent flying towards the enemy camp from an eruptor (mu pào), and when they get there a sound like a thunder-clap is heard, and flashes of light appear. If ten of these shells are fired successfully into the enemy camp, the whole place will be set ablaze...

Grenade-like devices were also known in ancient India. In a 12th-century Persian historiography, the Mojmal al-Tawarikh, a terracotta elephant filled with explosives set with a fuse was placed hidden in the van and exploded as the invading army approached.

The first cast-iron bombshells and grenades appeared in Europe in 1467, where their initial role was with the besieging and defense of castles and fortifications. A hoard of several hundred ceramic hand grenades was discovered during construction in front of a bastion of the Bavarian city of Ingolstadt, Germany, dated to the 17th century. Many of the grenades retained their original black powder loads and igniters. The grenades were most likely intentionally dumped in the moat of the bastion prior to 1723.

By the mid-17th century, infantry known as " grenadiers " began to emerge in the armies of Europe, who specialized in shock and close quarters combat, mostly with the usage of grenades and fierce melee combat. In 1643, it is possible that grenados were thrown amongst the Welsh at Holt Bridge during the English Civil War. The word grenade was also used during the events surrounding the Glorious Revolution in 1688, where cricket ball-sized (8.81 to 9 in (224 to 229 mm) in circumference) iron spheres packed with gunpowder and fitted with slow-burning wicks were first used against the Jacobites in the battles of Killiecrankie and Glen Shiel. These grenades were not very effective owing both to the unreliability of their fuse, as well inconsistent times to detonation, and as a result, saw little use. Grenades were also used during the Golden Age of Piracy, especially during boarding actions; pirate Captain Thompson used "vast numbers of powder flasks, grenade shells, and stinkpots" to defeat two pirate-hunters sent by the Governor of Jamaica in 1721.

Improvised grenades were increasingly used from the mid-19th century, the confines of trenches enhancing the effect of small explosive devices. In a letter to his sister, Colonel Hugh Robert Hibbert described an improvised grenade that was employed by British troops during the Crimean War (1854–1856):

We have a new invention to annoy our friends in their pits. It consists in filling empty soda water bottles full of powder, old twisted nails and any other sharp or cutting thing we can find at the time, sticking a bit of tow in for a fuse then lighting it and throwing it quickly into our neighbors' pit where it bursts, to their great annoyance. You may imagine their rage at seeing a soda water bottle come tumbling into a hole full of men with a little fuse burning away as proud as a real shell exploding and burying itself into soft parts of the flesh.

In March 1868 during the Paraguayan War, the Paraguayan troops used hand grenades in their attempt to board Brazilian ironclad warships with canoes.

Hand grenades were used on naval engagements during the War of the Pacific.

During the Siege of Mafeking in the Second Boer War, the defenders used fishing rods and a mechanical spring device to throw improvised grenades.

Improvised hand grenades were used to great effect by the Russian defenders of Port Arthur (now Lüshun Port) during the Russo-Japanese War.