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Composition and structure

Although white dwarfs are known with estimated masses as low as 0.17 M and as high as 1.33 M, the mass distribution is strongly peaked at 0.6 M, and the majority lie between 0.5 and 0.7 M. The estimated radii of observed white dwarfs are typically 0.8–2% the radius of the Sun; this is comparable to the Earth's radius of approximately 0.9% solar radius. A white dwarf, then, packs mass comparable to the Sun's into a volume that is typically a million times smaller than the Sun's; the average density of matter in a white dwarf must therefore be, very roughly, 1,000,000 times greater than the average density of the Sun, or approximately 10 g/cm, or 1 tonne per cubic centimetre. A typical white dwarf has a density of between 10 and 10 g/cm. White dwarfs are composed of one of the densest forms of matter known, surpassed only by other compact stars such as neutron stars, quark stars (hypothetical), and black holes.

White dwarfs were found to be extremely dense soon after their discovery. If a star is in a binary system, as is the case for Sirius B or 40 Eridani B, it is possible to estimate its mass from observations of the binary orbit. This was done for Sirius B by 1910, yielding a mass estimate of 0.94 M, which compares well with a more modern estimate of 1.00 M. Since hotter bodies radiate more energy than colder ones, a star's surface brightness can be estimated from its effective surface temperature, and that from its spectrum. If the star's distance is known, its absolute luminosity can also be estimated. From the absolute luminosity and distance, the star's surface area and its radius can be calculated. Reasoning of this sort led to the realization, puzzling to astronomers at the time, that due to their relatively high temperature and relatively low absolute luminosity, Sirius B and 40 Eridani B must be very dense. When Ernst Öpik estimated the density of a number of visual binary stars in 1916, he found that 40 Eridani B had a density of over 25,000 times the Sun 's, which was so high that he called it "impossible". As Arthur Eddington put it later, in 1927:

We learn about the stars by receiving and interpreting the messages which their light brings to us. The message of the companion of Sirius when it was decoded ran: "I am composed of material 3,000 times denser than anything you have ever come across; a ton of my material would be a little nugget that you could put in a matchbox." What reply can one make to such a message? The reply which most of us made in 1914 was — "Shut up. Don't talk nonsense."

As Eddington pointed out in 1924, densities of this order implied that, according to the theory of general relativity, the light from Sirius B should be gravitationally redshifted. This was confirmed when Adams measured this redshift in 1925.

Such densities are possible because white dwarf material is not composed of atoms joined by chemical bonds, but rather consists of a plasma of unbound nuclei and electrons. There is therefore no obstacle to placing nuclei closer than normally allowed by electron orbitals limited by normal matter. Eddington wondered what would happen when this plasma cooled and the energy to keep the atoms ionized was no longer sufficient. This paradox was resolved by R. H. Fowler in 1926 by an application of the newly devised quantum mechanics. Since electrons obey the Pauli exclusion principle, no two electrons can occupy the same state, and they must obey Fermi–Dirac statistics, also introduced in 1926 to determine the statistical distribution of particles which satisfy the Pauli exclusion principle. At zero temperature, therefore, electrons can not all occupy the lowest-energy, or ground, state; some of them would have to occupy higher-energy states, forming a band of lowest-available energy states, the Fermi sea. This state of the electrons, called degenerate, meant that a white dwarf could cool to zero temperature and still possess high energy.

Compression of a white dwarf will increase the number of electrons in a given volume. Applying the Pauli exclusion principle, this will increase the kinetic energy of the electrons, thereby increasing the pressure. This electron degeneracy pressure supports a white dwarf against gravitational collapse. The pressure depends only on density and not on temperature. Degenerate matter is relatively compressible; this means that the density of a high-mass white dwarf is much greater than that of a low-mass white dwarf and that the radius of a white dwarf decreases as its mass increases.

The existence of a limiting mass that no white dwarf can exceed without collapsing to a neutron star is another consequence of being supported by electron degeneracy pressure. Such limiting masses were calculated for cases of an idealized, constant density star in 1929 by Wilhelm Anderson and in 1930 by Edmund C. Stoner. This value was corrected by considering hydrostatic equilibrium for the density profile, and the presently known value of the limit was first published in 1931 by Subrahmanyan Chandrasekhar in his paper "The Maximum Mass of Ideal White Dwarfs". For a non-rotating white dwarf, it is equal to approximately 5.7 M / μ, where μ is the average molecular weight per electron of the star. As the carbon-12 and oxygen-16 which predominantly compose a carbon–oxygen white dwarf both have atomic numbers equal to half their atomic weight, one should take μ equal to 2 for such a star, leading to the commonly quoted value of 1.4 M. (Near the beginning of the 20th century, there was reason to believe that stars were composed chiefly of heavy elements, so, in his 1931 paper, Chandrasekhar set the average molecular weight per electron, μ, equal to 2.5, giving a limit of 0.91 M.) Together with William Alfred Fowler, Chandrasekhar received the Nobel Prize for this and other work in 1983. The limiting mass is now called the Chandrasekhar limit.

If a white dwarf were to exceed the Chandrasekhar limit, and nuclear reactions did not take place, the pressure exerted by electrons would no longer be able to balance the force of gravity, and it would collapse into a denser object called a neutron star. Carbon–oxygen white dwarfs accreting mass from a neighboring star undergo a runaway nuclear fusion reaction, which leads to a Type Ia supernova explosion in which the white dwarf may be destroyed, before it reaches the limiting mass.

New research indicates that many white dwarfs – at least in certain types of galaxies – may not approach that limit by way of accretion. It has been postulated that at least some of the white dwarfs that become supernovae attain the necessary mass by colliding with one another. It may be that in elliptical galaxies such collisions are the major source of supernovae. This hypothesis is based on the fact that the X-rays produced by those galaxies are 30 to 50 times less than what is expected to be produced by type Ia supernovas of that galaxy as matter accretes on the white dwarf from its encircling companion. It has been concluded that no more than 5 percent of the supernovae in such galaxies could be created by the process of accretion onto white dwarfs. The significance of this finding is that there could be two types of supernovae, which could mean that the Chandrasekhar limit might not always apply in determining when a white dwarf goes supernova, given that two colliding white dwarfs could have a range of masses. This in turn would confuse efforts to use exploding white dwarfs as standard candles in determining distances.

White dwarfs have low luminosity and therefore occupy a strip at the bottom of the Hertzsprung–Russell diagram, a graph of stellar luminosity versus color or temperature. They should not be confused with low-luminosity objects at the low-mass end of the main sequence, such as the hydrogen-fusing red dwarfs, whose cores are supported in part by thermal pressure, or the even lower-temperature brown dwarfs.