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Total internal reflection (1817–23)

By 1817 it had been discovered by Brewster, but not adequately reported, that plane-polarized light was partly depolarized by total internal reflection if initially polarized at an acute angle to the plane of incidence. Fresnel rediscovered this effect and investigated it by including total internal reflection in a chromatic-polarization experiment. With the aid of his first theory of chromatic polarization, he found that the apparently depolarized light was a mixture of components polarized parallel and perpendicular to the plane of incidence, and that the total reflection introduced a phase difference between them. Choosing an appropriate angle of incidence (not yet exactly specified) gave a phase difference of 1/8 of a cycle (45°). Two such reflections from the "parallel faces" of "two coupled prisms " gave a phase difference of 1/4 of a cycle (90°). These findings were contained in a memoir submitted to the Académie on 10 November 1817 and read a fortnight later. An undated marginal note indicates that the two coupled prisms were later replaced by a single "parallelepiped in glass"—now known as a Fresnel rhomb.

This was the memoir whose "supplement", dated January 1818, contained the method of superposing sinusoidal functions and the restatement of Malus's law in terms of amplitudes. In the same supplement, Fresnel reported his discovery that optical rotation could be emulated by passing the polarized light through a Fresnel rhomb (still in the form of "coupled prisms"), followed by an ordinary birefringent lamina sliced parallel to its axis, with the axis at 45° to the plane of reflection of the Fresnel rhomb, followed by a second Fresnel rhomb at 90° to the first. In a further memoir read on 30 March, Fresnel reported that if polarized light was fully "depolarized" by a Fresnel rhomb—now described as a parallelepiped—its properties were not further modified by a subsequent passage through an optically rotating medium or device.

The connection between optical rotation and birefringence was further explained in 1822, in the memoir on elliptical and circular polarization. This was followed by the memoir on reflection, read in January 1823, in which Fresnel quantified the phase shifts in total internal reflection, and thence calculated the precise angle at which a Fresnel rhomb should be cut in order to convert linear polarization to circular polarization. For a refractive index of 1.51, there were two solutions: about 48.6° and 54.6°.