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Fuel-containing materials

About 95% of the fuel in reactor No. 4 at the time of the accident. The radioactive material consists of core fragments, dust, and lava-like "fuel containing materials" (FCM)—also called " corium "—that flowed through the wrecked reactor building before hardening into a ceramic form.

Three different lavas are present in the basement of the reactor building: black, brown, and a porous ceramic. The lava materials are silicate glasses with inclusions of other materials within them. The porous lava is brown lava that dropped into water and thus cooled rapidly. It is unclear how long the ceramic form will retard the release of radioactivity. From 1997 to 2002, a series of published papers suggested that the self-irradiation of the lava would convert all 1,200 tonnes (1,200 long tons; 1,300 short tons) into a submicrometre and mobile powder within a few weeks.

It has been reported that the degradation of the lava is likely to be a slow, gradual process. The same paper states that the loss of uranium from the wrecked reactor is only 10 kg (22 lb) per year; this low rate of uranium leaching suggests that the lava is resisting its environment. The paper also states that when the shelter is improved, the leaching rate of the lava will decrease. As of 2021, some fuel had already degraded significantly. The famous elephant's foot, which originally was so hard that it required the use of an armor piercing AK-47 round to remove a chunk, had softened to a texture similar to sand.

Prior to the completion of the New Safe Confinement building, rainwater acted as a neutron moderator, triggering increased fission in the remaining materials, risking criticality. Gadolinium nitrate solution was used to quench neutrons to slow the fission. Even after completion of the building, fission reactions may be increasing; scientists are working to understand the cause and risks. While neutron activity has declined across most of the destroyed fuel, from 2017 until late 2020 a doubling in neutron density was recorded in the sub-reactor space, before levelling off in early 2021. This indicated increasing levels of fission as water levels dropped, the opposite of what had been expected, and atypical compared to other fuel-containing areas. The fluctuations have led to fears that a self-sustaining reaction could be created, which would likely spread more radioactive dust and debris throughout the New Safe Confinement, making future cleanup even more difficult. Potential solutions include using a robot to drill into the fuel and insert boron carbide control rods. In early 2021, a ChNPP press release stated that the observed increase in neutron densities had leveled off since the beginning of that year.