structural:scholar_edition, structural:expansion
Mercury-wetted relay

A mercury-wetted reed relay is a form of reed relay that employs a mercury switch, in which the contacts are wetted with mercury. Mercury reduces the contact resistance and mitigates the associated voltage drop. Surface contamination may result in poor conductivity for low-current signals. For high-speed applications, the mercury eliminates contact bounce, and provides virtually instantaneous circuit closure. Mercury wetted relays are position-sensitive and must be mounted according to the manufacturer's specifications. Because of the toxicity and expense of liquid mercury, these relays have increasingly fallen into disuse.

The high speed of switching action of the mercury-wetted relay is a notable advantage. The mercury globules on each contact coalesce, and the current rise time through the contacts is generally considered to be a few picoseconds. However, in a practical circuit it may be limited by the inductance of the contacts and wiring. It was quite common, before restrictions on the use of mercury, to use a mercury-wetted relay in the laboratory as a convenient means of generating fast rise time pulses, however although the rise time may be picoseconds, the exact timing of the event is, like all other types of relay, subject to considerable jitter, possibly milliseconds, due to mechanical variations.

The same coalescence process causes another effect, which is a nuisance in some applications. The contact resistance is not stable immediately after contact closure, and drifts, mostly downwards, for several seconds after closure, the change perhaps being 0.5 ohm.