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Chemical classification and petrology

When it is impractical to classify a volcanic rock by mineralogy, the rock must be classified chemically.

There are relatively few minerals that are important in the formation of common igneous rocks, because the magma from which the minerals crystallize is rich in only certain elements: silicon, oxygen, aluminium, sodium, potassium, calcium, iron, and magnesium. These are the elements that combine to form the silicate minerals, which account for over ninety percent of all igneous rocks. The chemistry of igneous rocks is expressed differently for major and minor elements and for trace elements. Contents of major and minor elements are conventionally expressed as weight percent oxides (e.g., 51% SiO, and 1.50% TiO). Abundances of trace elements are conventionally expressed as parts per million by weight (e.g., 420 ppm Ni, and 5.1 ppm Sm). The term "trace element" is typically used for elements present in most rocks at abundances less than 100 ppm or so, but some trace elements may be present in some rocks at abundances exceeding 1,000 ppm. The diversity of rock compositions has been defined by a huge mass of analytical data—over 230,000 rock analyses can be accessed on the web through a site sponsored by the U. S. National Science Foundation (see the External Link to EarthChem).

The single most important component is silica, SiO, whether occurring as quartz or combined with other oxides as feldspars or other minerals. Both intrusive and volcanic rocks are grouped chemically by total silica content into broad categories.

This classification is summarized in the following table:

The percentage of alkali metal oxides (Na O plus K O) is second only to silica in its importance for chemically classifying volcanic rock. The silica and alkali metal oxide percentages are used to place volcanic rock on the TAS diagram, which is sufficient to immediately classify most volcanic rocks. Rocks in some fields, such as the trachyandesite field, are further classified by the ratio of potassium to sodium (so that potassic trachyandesites are latites and sodic trachyandesites are benmoreites). Some of the more mafic fields are further subdivided or defined by normative mineralogy, in which an idealized mineral composition is calculated for the rock based on its chemical composition. For example, basanite is distinguished from tephrite by having a high normative olivine content.

Other refinements to the basic TAS classification include:

In older terminology, silica oversaturated rocks were called silicic or acidic where the SiO was greater than 66% and the family term quartzolite was applied to the most silicic. A normative feldspathoid classifies a rock as silica-undersaturated; an example is nephelinite.

Magmas are further divided into three series:

The alkaline series is distinguishable from the other two on the TAS diagram, being higher in total alkali oxides for a given silica content, but the tholeiitic and calc-alkaline series occupy approximately the same part of the TAS diagram. They are distinguished by comparing total alkali with iron and magnesium content.

These three magma series occur in a range of plate tectonic settings. Tholeiitic magma series rocks are found, for example, at mid-ocean ridges, back-arc basins, oceanic islands formed by hotspots, island arcs and continental large igneous provinces.

All three series are found in relatively close proximity to each other at subduction zones where their distribution is related to depth and the age of the subduction zone. The tholeiitic magma series is well represented above young subduction zones formed by magma from relatively shallow depth. The calc-alkaline and alkaline series are seen in mature subduction zones, and are related to magma of greater depths. Andesite and basaltic andesite are the most abundant volcanic rock in island arc which is indicative of the calc-alkaline magmas. Some island arcs have distributed volcanic series as can be seen in the Japanese island arc system where the volcanic rocks change from tholeiite—calc-alkaline—alkaline with increasing distance from the trench.