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Surface composition

Io's colorful appearance is the result of materials deposited by its extensive volcanism, including silicates (such as orthopyroxene), sulfur, and sulfur dioxide. Sulfur dioxide frost is ubiquitous across the surface of Io, forming large regions covered in white or grey materials. Sulfur is also seen in many places across Io, forming yellow to yellow-green regions. Sulfur deposited in the mid-latitude and polar regions is often damaged by radiation, breaking up the normally stable cyclic 8-chain sulfur. This radiation damage produces Io's red-brown polar regions.

Explosive volcanism, often taking the form of umbrella-shaped plumes, paints the surface with sulfurous and silicate materials. Plume deposits on Io are often colored red or white depending on the amount of sulfur and sulfur dioxide in the plume. Generally, plumes formed at volcanic vents from degassing lava contain a greater amount of S, producing a red "fan" deposit, or in extreme cases, large (often reaching beyond 450 km or 280 mi from the central vent) red rings. A prominent example of a red-ring plume deposit is located at Pele. These red deposits consist primarily of sulfur (generally 3- and 4-chain molecular sulfur), sulfur dioxide, and perhaps sulfuryl chloride. Plumes formed at the margins of silicate lava flows (through the interaction of lava and pre-existing deposits of sulfur and sulfur dioxide) produce white or gray deposits.

Compositional mapping and Io's high density suggest that Io contains little to no water, though small pockets of water ice or hydrated minerals have been tentatively identified, most notably on the northwest flank of the mountain Gish Bar Mons. Io has the least amount of water of any known body in the Solar System. This lack of water is likely due to Jupiter being hot enough early in the evolution of the Solar System to drive off volatile materials like water in the vicinity of Io, but not hot enough to do so farther out.