structural:expansion
Steel

The Bessemer process, invented by Sir Henry Bessemer, allowed the mass-production of steel, increasing the scale and speed of production of this vital material, and decreasing the labor requirements. The key principle was the removal of excess carbon and other impurities from pig iron by oxidation with air blown through the molten iron. The oxidation also raises the temperature of the iron mass and keeps it molten.

The "acid" Bessemer process had a serious limitation in that it required relatively scarce hematite ore which is low in phosphorus. Sidney Gilchrist Thomas developed a more sophisticated process to eliminate the phosphorus from iron. Collaborating with his cousin, Percy Gilchrist a chemist at the Blaenavon Ironworks, Wales, he patented his process in 1878; Bolckow Vaughan & Co. in Yorkshire was the first company to use his patented process. His process was especially valuable on the continent of Europe, where the proportion of phosphoric iron was much greater than in England, and both in Belgium and in Germany the name of the inventor became more widely known than in his own country. In America, although non-phosphoric iron largely predominated, an immense interest was taken in the invention.

The next great advance in steel making was the Siemens–Martin process. Sir Charles William Siemens developed his regenerative furnace in the 1850s, for which he claimed in 1857 to able to recover enough heat to save 70–80% of the fuel. The furnace operated at a high temperature by using regenerative preheating of fuel and air for combustion. Through this method, an open-hearth furnace can reach temperatures high enough to melt steel, but Siemens did not initially use it in that manner.

French engineer Pierre-Émile Martin was the first to take out a license for the Siemens furnace and apply it to the production of steel in 1865. The Siemens–Martin process complemented rather than replaced the Bessemer process. Its main advantages were that it did not expose the steel to excessive nitrogen (which would cause the steel to become brittle), it was easier to control, and that it permitted the melting and refining of large amounts of scrap steel, lowering steel production costs and recycling an otherwise troublesome waste material. It became the leading steel making process by the early 20th century.

The availability of cheap steel allowed building larger bridges, railroads, skyscrapers, and ships. Other important steel products—also made using the open hearth process—were steel cable, steel rod and sheet steel which enabled large, high-pressure boilers and high-tensile strength steel for machinery which enabled much more powerful engines, gears and axles than were previously possible. With large amounts of steel it became possible to build much more powerful guns and carriages, tanks, armored fighting vehicles and naval ships.