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Chemistry

Faraday's earliest chemical work was as an assistant to Humphry Davy. Faraday was involved in the study of chlorine; he discovered two new compounds of chlorine and carbon: hexachloroethane which he made via the chlorination of ethylene and carbon tetrachloride from the decomposition of the former. He also conducted the first rough experiments on the diffusion of gases, a phenomenon that was first pointed out by John Dalton. The physical importance of this phenomenon was more fully revealed by Thomas Graham and Joseph Loschmidt. Faraday succeeded in liquefying several gases, investigated the alloys of steel, and produced several new kinds of glass intended for optical purposes. A specimen of one of these heavy glasses subsequently became historically important; when the glass was placed in a magnetic field Faraday determined the rotation of the plane of polarisation of light. This specimen was also the first substance found to be repelled by the poles of a magnet.

Faraday invented an early form of what was to become the Bunsen burner, which is still in practical use in science laboratories around the world as a convenient source of heat. Faraday worked extensively in the field of chemistry, discovering chemical substances such as benzene (which he called bicarburet of hydrogen) and liquefying gases such as chlorine. The liquefying of gases helped to establish that gases are the vapours of liquids possessing a very low boiling point and gave a more solid basis to the concept of molecular aggregation. In 1820 Faraday reported the first synthesis of compounds made from carbon and chlorine, C Cl and CCl, and published his results the following year. Faraday also determined the composition of the chlorine clathrate hydrate, which had been discovered by Humphry Davy in 1810. Faraday is also responsible for discovering the laws of electrolysis, and for popularising terminology such as anode, cathode, electrode, and ion, terms proposed in large part by William Whewell.

Faraday was the first to report what later came to be called metallic nanoparticles. In 1847 he discovered that the optical properties of gold colloids differed from those of the corresponding bulk metal. This was probably the first reported observation of the effects of quantum size, and might be considered to be the birth of nanoscience.