quality:corruption
Sulfide ores

The ores of base metals are often sulfides. In recent centuries, reverberatory furnaces have been used to keep the charge being smelted separately from the fuel. Traditionally, they were used for the first step of smelting: forming two liquids, one an oxide slag containing most of the impurities, and the other a sulfide matte containing the valuable metal sulfide and some impurities. Such "reverb" furnaces are today about 40 meters long, 3 meters high, and 10 meters wide. Fuel is burned at one end to melt the dry sulfide concentrates (usually after partial roasting) which are fed through openings in the roof of the furnace. The slag floats over the heavier matte and is removed and discarded or recycled. The sulfide matte is then sent to the converter. The precise details of the process vary from one furnace to another depending on the mineralogy of the ore body.

While reverberatory furnaces produced slags containing very little copper, they were relatively energy inefficient and off-gassed a low concentration of sulfur dioxide that was difficult to capture; a new generation of copper smelting technologies has supplanted them. More recent furnaces exploit bath smelting, top-jetting lance smelting, flash smelting, and blast furnaces. Some examples of bath smelters include the Noranda furnace, the Isasmelt furnace, the Teniente reactor, the Vunyukov smelter, and the SKS technology. Top-jetting lance smelters include the Mitsubishi smelting reactor. Flash smelters account for over 50% of the world's copper smelters. There are many more varieties of smelting processes, including the Kivset, Ausmelt, Tamano, EAF, and BF.