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Speed of sound in ideal gases and air

Numerical substitution of the above values gives the ideal gas approximation of sound velocity for gases, which is accurate at relatively low gas pressures and densities (for air, this includes standard Earth sea-level conditions). Also, for diatomic gases the use of γ = 1.4000 requires that the gas exists in a temperature range high enough that rotational heat capacity is fully excited (i.e., molecular rotation is fully used as a heat energy "partition" or reservoir); but at the same time the temperature must be low enough that molecular vibrational modes contribute no heat capacity (i.e., insignificant heat goes into vibration, as all vibrational quantum modes above the minimum-energy-mode have energies that are too high to be populated by a significant number of molecules at this temperature). For air, these conditions are fulfilled at room temperature, and also temperatures considerably below room temperature (see tables below). See the section on gases in specific heat capacity for a more complete discussion of this phenomenon.