structural:scholar_edition, information:extraction, information:filtering
A thermodynamic potential is a scalar quantity used to represent the thermodynamic state of a system. Just as in mechanics, where potential energy is defined as capacity to do work, similarly different potentials have different meanings. The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886. Josiah Willard Gibbs in his papers used the term fundamental functions. While thermodynamic potentials cannot be measured directly, they can be predicted using computational chemistry. One main thermodynamic potential that has a physical interpretation is the internal energy U. It is the energy of configuration of a given system of conservative forces and only has meaning with respect to a defined set of references. Expressions for all other thermodynamic energy potentials are derivable via Legendre transforms from an expression for U. In other words, each thermodynamic potential is equivalent to other thermodynamic potentials; each potential is a different expression of the others. In thermodynamics, external forces, such as gravity, are counted as contributing to total energy rather than to thermodynamic potentials. For example, the working fluid in a steam engine sitting on top of Mount Everest has higher total energy due to gravity than it has at the bottom of the Mariana Trench, but the same thermodynamic potentials. This is because the gravitational potential energy belongs to the total energy rather than to thermodynamic potentials such as internal energy.