* [[Coco Chanel]] (1937)<ref name=":5" />
* [[Suzy Parker]] (1957)<ref>[https://inside.chanel.com/en/no5/campaigns/1957_no5_parker "1957 – Suzy Parker, photographed by Richard Avedon for CHANEL N°5 advertising campaign in 1957"]. ''Inside CHANEL''. Retrieved 1 March 2020.</ref>
* [[Ali MacGraw]] (1966)<ref>[https://inside.chanel.com/en/no5/campaigns/1966_no5_mcgraw "1966 – Ali MacGraw, photographed by Jérôme Ducrot for CHANEL N°5 advertising campaign in 1966"]. ''Inside CHANEL''. Retrieved 1 March 2020.</ref>
* [[Jean Shrimpton]] (1971)<ref>[https://inside.chanel.com/en/no5/campaigns/1971_no5_shrimpton "1971 – Jean Shrimpton, photographed by Helmut Newton for CHANEL N°5 advertising campaign in 1971"]. ''Inside CHANEL''. Retrieved 1 March 2020.</ref>
* [[Catherine Deneuve]] (1969-1979)<ref>Bousquet, Elodie (15 October 2012). [https://www.lexpress.fr/styles/parfums/video-chanel-n-5-en-12-publicites-cultes_1174556.html "VIDEOS. Chanel N°5 et ses publicités cultes"]. ''L'Express'' (in French).</ref><ref>[https://inside.chanel.com/en/no5/campaigns/1972_no5_deneuve "1972 – Catherine Deneuve, photographed by Richard Avedon for a CHANEL N°5 campaign in 1972 that was shown exclusively in the United States"]. ''Inside CHANEL''. Retrieved 1 March 2020.</ref>
* [[Carole Bouquet]] (1986-1997)<ref>[https://inside.chanel.com/en/no5/campaigns/1986_no5_monuments "CHANEL N°5 advertising film from 1986, "Monuments"], by Ridley Scott, with Carole Bouquet". ''Inside CHANEL''. Retrieved 1 March 2020</ref><ref>[https://inside.chanel.com/en/no5/campaigns/1997_no5_e_bouquet "1997 – Carole Bouquet, photographed by Dominique Issermann for CHANEL N°5 advertising campaign in 1997"]. Retrieved 1 March 2020.</ref>
* [[Estella Warren]] (1998-2000)<ref>[https://inside.chanel.com/en/no5/campaigns/1998_no5_le_loup "CHANEL N°5 advertising film from 1998, "Le Loup"], by Luc Besson, with Estella Warren". ''Inside CHANEL''. Retrieved 1 March 2020.</ref><ref>[https://inside.chanel.com/en/no5/campaigns/2000_no5_warren "2000 – Estella Warren, photographed by Jean-Paul Goude for CHANEL N°5 advertising campaign"]. ''Inside CHANEL''. Retrieved 1 March 2020.</ref>
* [[Nicole Kidman]] (2004-2005)<ref>Friedman, Vanessa (10 November 2004). [https://www.nytimes.com/2004/11/10/business/coming-soon-nicole-kidman-to-chanel-no-5.html "Coming Soon, Nicole Kidman to Chanel No. 5".] ''The New York Times''.</ref><ref>[https://inside.chanel.com/en/no5/campaigns/2005_no5_kidman "2005 – Nicole Kidman, photographed by Baz Luhrmann for CHANEL N°5 advertising campaign in 2005"]. Retrieved 1 March 2020.</ref>
* [[Audrey Tautou]] (2009)<ref>[https://www.ellecanada.com/beauty/star-scent-audrey-tautou-is-the-new-face-of-chanel-no-5 "Star scent: Audrey Tautou is the new face of Chanel No.5"]. ''Elle Canada''. 1 April 2009.</ref>
* [[Brad Pitt]] (2012)<ref name=":6" />
* [[Marilyn Monroe]] (2013)<ref>[https://inside.chanel.com/en/no5/campaigns/2013_no5_marilyn_and_n5 "2013 – Marilyn reveals the truth behind her legendary statement. "Marilyn and N°5" (30" version)"]. ''Inside CHANEL''. Retrieved 1 March 2020.</ref>
* [[Gisele Bündchen|Gisele Bundchen]] (2014)<ref>[http://fashion.telegraph.co.uk/beauty/news-features/TMG10851135/Gisele-Bundchen-is-the-new-face-of-Chanel-No-5.html "Gisele Bundchen is the new face of Chanel No. 5"]. ''Telegraph''. 23 May 2014.</ref>
* [[Lily-Rose Depp]] (2016-2019)<ref>[https://www.elle.com/uk/beauty/beauty-tips/a30609/lily-rose-depp-is-the-new-face-of-chanel-no5/ "Lily-Rose Depp Is The New Face of Chanel No.5"]. ''Elle UK''. 23 May 2016.</ref><ref>[https://www.papermag.com/lily-rose-depp-chanel-holiday-2641153184.html "Watch Lily-Rose Depp Transform in Chanel's New Holiday Film"]. ''Paper Magazine''. 29 October 2019.</ref>
* [[Marion Cotillard]] (2020-nuværende)<ref name=":7" />
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