Henrique mødte nykommeren Dmitrii Smolyakov den 23. juli 2016 på UFC på Fox 20.<ref>{{Cite web|url=http://www.mmafighting.com/2016/4/4/11365496/alex-oliveira-vs-james-moontasri-luis-henrique-vs-dmitry-smolyakov|title=Alex Oliveira vs. James Moonstasri, Luis Henrique vs. Dmitry Smolyakov set for UFC on Fox 20|publisher=mmafighting.com|last=Guilherme Cruz|date=2016-03-14|access-date=2017-01-09}}</ref> Han vandt kampen via submission i anden omgang.<ref>{{Cite web|url=http://mmajunkie.com/2016/07/ufc-on-fox-20-results-luis-henrique-taps-exhausted-dmitrii-smoliakov-in-second-round|title=Luis Henrique taps exhausted Dmitrii Smoliakov in second round|publisher=mmajunkie.com|last=Steven Marrocco|date=2016-06-23|access-date=2017-01-09}}</ref>
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