{| class="wikitable" style="margin-left:1em;"
|-
! År
! Mestre
! Finalister
! Finaleresultat
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2014|2014]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|COL|3:2}} [[Juan Sebastián Cabal]]<br/>{{flagikon|COL|3:2}} [[Robert Farah]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ESP|3:2}} [[David Marrero]]<br/>{{flagikon|BRA|3:2}} [[Marcelo Melo]]
| style="padding-left:7px; padding-right:20px;"|6–4, 6–2
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2015|2015]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|SVK|3:2}} [[Martin Kližan]]<br/>{{flagikon|AUT|3:2}} [[Philipp Oswald]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ESP|3:2}} [[Pablo Andújar]]<br/>{{flagikon|AUT|3:2}} [[Oliver Marach]]
| style="padding-left:7px; padding-right:20px;"|7–6(3), 6–4
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2016|2016]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|COL|3:2}} [[Juan Sebastián Cabal]] {{small|(2)}}<br/>{{flagikon|COL|3:2}} [[Robert Farah]] {{small|(2)}}
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ESP|3:2}} [[Pablo Carreño Busta]]<br/>{{flagikon|ESP|3:2}} [[David Marrero]]
| style="padding-left:7px; padding-right:20px;"|7–6(2), 6–4
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2017|2017]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ESP|3:2}} [[Pablo Carreño Busta]]<br/>{{flagikon|URU|3:2}} [[Pablo Cuevas]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|COL|3:2}} [[Juan Sebastián Cabal]]<br/>{{flagikon|COL|3:2}} [[Robert Farah]]
| style="padding-left:7px; padding-right:20px;"|6–4, 5–7, [10–8]
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2018|2018]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ESP|3:2}} [[David Marrero]]<br/>{{flagikon|ESP|3:2}} [[Fernando Verdasco]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|CRO|3:2}} [[Nikola Mektić]]<br/>{{flagikon|AUT|3:2}} [[Alexander Peya]]
| style="padding-left:7px; padding-right:20px;"|5–7, 7–5, [10–8]
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2019|2019]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ARG|3:2}} [[Máximo González]]<br/>{{flagikon|CHI|3:2}} [[Nicolás Jarry]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|BRA|3:2}} [[Thomaz Bellucci]]<br/>{{flagikon|BRA|3:2}} [[Rogério Dutra Silva]]
| style="padding-left:7px; padding-right:20px;"|6–7(3), 6–3, [10–7]
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2020|2020]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ESP|3:2}} [[Marcel Granollers]]<br/>{{flagikon|ARG|3:2}} [[Horacio Zeballos]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ITA|3:2}} [[Salvatore Caruso]]<br/>{{flagikon|ITA|3:2}} [[Federico Gaio]]
| style="padding-left:7px; padding-right:20px;"|6–4, 5–7, [10–7]
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[2021]]
| colspan="3" style="padding-left:7px; padding-right:20px;"|Aflyst pga. [[COVID-19-pandemien]]
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2022|2022]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ITA|3:2}} [[Simone Bolelli]]<br/>{{flagikon|ITA|3:2}} [[Fabio Fognini]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|GBR|3:2}} [[Jamie Murray]]<br/>{{flagikon|BRA|3:2}} [[Bruno Soares]]
| style="padding-left:7px; padding-right:20px;"|7–5, 6–7(2), [10–6]
|-
| style="text-align:center; padding-left:15px; padding-right:15px;"|[[Rio Open 2023|2023]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|ARG|3:2}} [[Máximo González]] {{small|(2)}}<br/>{{flagikon|ARG|3:2}} [[Andrés Molteni]]
| style="padding-left:5px; padding-right:20px;"|{{flagikon|COL|3:2}} [[Juan Sebastián Cabal]]<br/>{{flagikon|BRA|3:2}} [[Marcelo Melo]]
| style="padding-left:7px; padding-right:20px;"|6–1, 7–6(3)
|}
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