Instruct: Identify the main and secondary category of Arxiv papers based on the titles and abstracts
Query: Catalysis by Dark States in Vibropolaritonic Chemistry   Collective strong coupling between a disordered ensemble of $N$ localized
molecular vibrations and a resonant optical cavity mode gives rise to 2
polariton and $N-1\gg2$ dark modes. Thus, experimental changes in
thermally-activated reaction kinetics due to polariton formation appear
entropically unlikely and remain a puzzle. Here we show that the overlooked
dark modes, while parked at the same energy as bare molecular vibrations, are
robustly delocalized across $\sim$2-3 molecules, yielding enhanced channels of
vibrational cooling, concomitantly catalyzing a chemical reaction. As an
illustration, we theoretically show a $\approx$50\% increase in an electron
transfer rate due to enhanced product stabilization. The reported effects can
arise when the homogeneous linewidths of the dark modes are smaller than their
energy spacings.

37
The categories of this paper are: supr-con
2
The categories of this paper are: math
32
The categories of this paper are: atom-ph
10
The categories of this paper are: q-bio
29
The categories of this paper are: funct-an
4
The categories of this paper are: cond-mat
16
The categories of this paper are: stat
12
The categories of this paper are: nucl-th
25
The categories of this paper are: patt-sol
8
The categories of this paper are: hep-ex
28
The categories of this paper are: alg-geom
23
The categories of this paper are: solv-int
9
The categories of this paper are: nlin
0
The categories of this paper are: hep-ph
22
The categories of this paper are: chao-dyn
35
The categories of this paper are: mtrl-th