Instruct: Identify the main and secondary category of Arxiv papers based on the titles and abstracts
Query: Concentration Dependence of Superconductivity and Order-Disorder
  Transition in the Hexagonal Rubidium Tungsten Bronze RbxWO3. Interfacial and
  bulk properties   We revisited the problem of the stability of the superconducting state in
RbxWO3 and identified the main causes of the contradictory data previously
published. We have shown that the ordering of the Rb vacancies in the
nonstoichiometric compounds have a major detrimental effect on the
superconducting temperature Tc.The order-disorder transition is first order
only near x = 0.25, where it cannot be quenched effectively and Tc is reduced
below 1K. We found that the high Tc's which were sometimes deduced from
resistivity measurements, and attributed to compounds with .25 < x < .30, are
to be ascribed to interfacial superconductivity which generates spectacular
non-linear effects. We also clarified the effect of acid etching and set more
precisely the low-rubidium-content boundary of the hexagonal phase.This work
makes clear that Tc would increase continuously (from 2 K to 5.5 K) as we
approach this boundary (x = 0.20), if no ordering would take place - as its is
approximately the case in CsxWO3. This behaviour is reminiscent of the
tetragonal tungsten bronze NaxWO3 and asks the same question : what mechanism
is responsible for this large increase of Tc despite the considerable
associated reduction of the electron density of state ? By reviewing the other
available data on these bronzes we conclude that the theoretical models which
are able to answer this question are probably those where the instability of
the lattice plays a major role and, particularly, the model which call upon
local structural excitations (LSE), associated with the missing alkali atoms.

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The categories of this paper are: chem-ph
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The categories of this paper are: hep-lat
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The categories of this paper are: gr-qc
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The categories of this paper are: comp-gas
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The categories of this paper are: solv-int
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The categories of this paper are: bayes-an
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The categories of this paper are: q-fin
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The categories of this paper are: nucl-ex
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The categories of this paper are: mtrl-th
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The categories of this paper are: supr-con
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The categories of this paper are: dg-ga
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The categories of this paper are: math
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The categories of this paper are: quant-ph
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The categories of this paper are: ao-sci
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The categories of this paper are: econ
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The categories of this paper are: funct-an