CREATE TABLE table_68486 ("Episode" TEXT, "First aired" TEXT, "Entrepreneur ( s ) " TEXT, "Company or product name" TEXT, "Money requested  ( \\u00a3 ) " FLOAT, "Investing Dragon ( s ) " TEXT)

Name the first aired with money requested more than 85,000
SELECT "First aired" FROM table_68486 WHERE "Money requested (\u00a3)" > '85,000'
SELECT "First aired" FROM "table_68486" WHERE "Money requested (\u00a3)" > '85,000'